Propriétés Physico-Chimiques de Composés à Caractère Aromatique VII Étude par L.C.A.O. de l'intensité et de la position de la transition 1La de composés monoaza-aromatiques(1)
✍ Scribed by J. Nasielski; E. Vander Donckt
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 514 KB
- Volume
- 72
- Category
- Article
- ISSN
- 0037-9646
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The electronic energy levels of a series of ethyl esters derived from aromatic polycyclic carboxylic acids have been computed by the LCAO method. A good correlation with polarographic half-wave potentials and with UV absorption spectra is obtained. La mCthode des orbitales moleculaires (LCAO MO) a
The frequencies of the 'L, transitions of polycyclic aromatic aldehydes are related linearly to the energy gap between the highest bonding and the lowest anti-bonding orbitals in these molecules calculated by an iterative Huckel-L. C. A.0.-method. Solutions of the same derivatives and tetracyanoethy