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Proposed molecular structures for 3-butenenitrile, 2-methyl-3-butenenitrile, and 3-methyl-3-butenenitrile

✍ Scribed by D.A.C. Compton


Book ID
119115655
Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
375 KB
Volume
87
Category
Article
ISSN
0166-1280

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The cyclodimerisation of 3-methyl-2-bute
✍ H Tucker; G Golding; SR Purvis πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 French βš– 168 KB

3-Methyl-2-butenenitrile (1) cyclodimerised on treatment with lithium diisopropylamide in dimethoxyethane at temperatures between -78Β°C and 0Β°C to 3-amino-4-cyano-1,5,5trimethyl-1,3-cyclohexadiene (2) the structure of which was established by acid hydrolysis to the known 4-cyano-1,5,5-trimethyl-1-cy