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Nickel Complexes Involved in the Isomerization of 2-Methyl-3-butenenitrile

✍ Scribed by Acosta-Ramírez, Alberto; Flores-Gaspar, Areli; Muñoz-Hernández, Miguel; Arévalo, Alma; Jones, William D.; García, Juventino J.


Book ID
126072311
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
188 KB
Volume
26
Category
Article
ISSN
0276-7333

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The catalytic isomerization reactions of
✍ Christophe Vallée; Christine Valério; Yves Chauvin; Gerald P Niccolai; Jean-Mari 📂 Article 📅 2004 🏛 Elsevier Science 🌐 English ⚖ 326 KB

The catalytic isomerization reaction of 2-methyl-3-butenenitrile (2M3BN) into 3-pentenenitrile (3PN) has been performed in the presence of Ni(0) and phosphine complexes and in biphasic ionic liquid/organic solvent. Several neutral and ionic phosphines and ionic liquids have been tested, the best res