Properties of semicrystalline polyolefins. IV. Crystallization phenomena in poly-3-methyl-1-butene
β Scribed by I. Kirshenbaum; W. C. Feist; R. B. Isaacson
- Publisher
- John Wiley and Sons
- Year
- 1965
- Tongue
- English
- Weight
- 884 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0021-8995
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β¦ Synopsis
A study has been carried out of the physical and mechanical properties and crystallization behavior of poly-&methyl-1-butene (poly-3-MB). The melt behavior of poly-3-MB waa examined by means of the depolarised light intensity (DLI) technique. These birefringence studies indicated the onset of motion in the crystalline phase of poly-3-MB at about 100Β°C. (over 200Β°C. below the melting point). These studies also showed that limited molecdr motion may occur at room temperature, i.e., about 25Β°C. below the glass transition temperature of poly-3-MB.
π SIMILAR VOLUMES
Several works have appeared in recent years on the structure of (poly)3MB1 but showing remarkable divergence concerning the crystal lattice of this polymer. Particularly, in a paper by Huguet the structure is interpreted on the basis of a tetragonal lattice, which is here shown to be unacceptable.
## Abstract The triazoline derivative 1 was used as an additive in the chainβgrowth controlled radical polymerization of vinylic monomers to afford narrowly distributed polymers. This new system is applicable to styrene as well as to methacrylates. The monomer consumption and the variation of the m