The mobilities of Na+, Cl-and OH-ions and water in Nation 120 membrane have been discussed. According to the frictional formalism they have been expressed in terms of friction coefficients describing single interactions between components of the system. The signiticant influence of the movement of w
Properties of composite membranes from ion exchange membranes and conducting polymers—I. Conductivity of composite membrane from cation exchange membranes and polypyrrole
✍ Scribed by Toshikatsu Sata
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 806 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0013-4686
No coin nor oath required. For personal study only.
✦ Synopsis
In order to prepare a free-standing polypyrrole hhn with high mechanical strength, Fe(II1) form or Cu(I1) form cation exchange membranes were immersed in an aqueous pyrrole solution. Polymerization speed of pyrrole in the Fe(II1) form membrane was faster than that in the Cu(I1) form membrane. A linear relationship was observed between conductivity of the composite membrane and immersion period in the pyrrole solution. Conductivity of the composite membrane from the Fe(II1) form membrane reached about 10e3 Scm-', which was the ultimate vahte of this method. Properties of formed polypyrrole in the membrane matrix was discussed in relation to weight increase of the membrane and species of oxidative cation. Burst strength of the composite membrane increased with increasing polymerization period of pyrrole.
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