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Properties of composite membranes from ion exchange membranes and conducting polymers—I. Conductivity of composite membrane from cation exchange membranes and polypyrrole

✍ Scribed by Toshikatsu Sata


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
806 KB
Volume
39
Category
Article
ISSN
0013-4686

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✦ Synopsis


In order to prepare a free-standing polypyrrole hhn with high mechanical strength, Fe(II1) form or Cu(I1) form cation exchange membranes were immersed in an aqueous pyrrole solution. Polymerization speed of pyrrole in the Fe(II1) form membrane was faster than that in the Cu(I1) form membrane. A linear relationship was observed between conductivity of the composite membrane and immersion period in the pyrrole solution. Conductivity of the composite membrane from the Fe(II1) form membrane reached about 10e3 Scm-', which was the ultimate vahte of this method. Properties of formed polypyrrole in the membrane matrix was discussed in relation to weight increase of the membrane and species of oxidative cation. Burst strength of the composite membrane increased with increasing polymerization period of pyrrole.


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