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Propellanes: The reaction of cyclopentadienyl cobalt complexes of tetraenic propellanes with 4-methyl-3,5-dioxo-triazolinedione (MTAD)

✍ Scribed by Pnina Ashkenazi; Moshe Kapon; David Ginsburg

Book ID: 104203782
Publisher: Elsevier Science
Year: 1988
Tongue: French
Weight: 485 KB
Volume: 44
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(01)86185-8

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✦ Synopsis

urtrtct -KMD IB ibtt. to rtplace CpcO moieties cooplexed to 1,3ditntm, affordiog the corrtmpondlng Diclr-Alder adduct* of these dienea. ** Dcdtcated fn frleodrhlp to tn organocobaltophlle, Professor hlbert Eachennooer, in honor of his seminal contributions to tht chemistry of much more complex cobalt compounds.

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## Abstract Singlet oxygen attacks **3** from the direction __syn__ to the hetero‐ring.

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## Abstract Reactions of 11‐substituted‐1, 6‐methano [10]annulenes and 1, 6‐methano [10]‐annulenes substituted in the aromatic ring with the title dienophile are described.