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Propagation Rate of the Cationic Polymerization of 2,4,6-Trimethylstyrene: A Linear Free Energy Approach

โœ Scribed by Mayr, Herbert; Ofial, Armin R.; Schimmel, Holger

Book ID
125843146
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
171 KB
Volume
38
Category
Article
ISSN
0024-9297

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Evaluation of propagation rate constants
Evaluation of propagation rate constants for the free radical polymerization of methacrylonitrile by pulsed laser photolysis
โœ Devon A. Shipp; Trevor A. Smith; David H. Solomon; Graeme Moad ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 411 KB

## Abstract Propagation rate constants for the free radical polymerization of methacrylonitrile (MAN) have been obtained by pulsed laser photolysis (PLP). The temperature dependence of the propagation rate constants indicates a frequency factor of 10^(6,43 ยฑ 0,26)^ L ยท mol^โˆ’1^ ยท s^โˆ’1^ and an activa