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Rate constant for the propagation of the polymerization of α-methylstyrene by the free anion in tetrahydrofuran and tetrahydropyran

✍ Scribed by Comyn, J. ;Dainton, F. S. ;Harpell, G. A. ;Hui, K. M. ;Ivin, K. J.

Publisher
Wiley (John Wiley & Sons)
Year
1967
Tongue
English
Weight
109 KB
Volume
5
Category
Article
ISSN
0449-2986

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Evaluation of propagation rate constants
Evaluation of propagation rate constants for the free radical polymerization of methacrylonitrile by pulsed laser photolysis
✍ Devon A. Shipp; Trevor A. Smith; David H. Solomon; Graeme Moad 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 411 KB

## Abstract Propagation rate constants for the free radical polymerization of methacrylonitrile (MAN) have been obtained by pulsed laser photolysis (PLP). The temperature dependence of the propagation rate constants indicates a frequency factor of 10^(6,43 ± 0,26)^ L · mol^−1^ · s^−1^ and an activa