The free radical propagation rate coefficients of both Methyl Methacrylate (MMA) and Styrene (STY) have been measured using Pulsed-Laser Polymerization. The effect of solvents on the propagation rate coefficient, k p , is reported for several solvents, namely, bromobenzene, chlorobenzene, dimethyl s
Propagation Rate Coefficients of Styrene and Methyl Methacrylate in Supercritical CO2
β Scribed by van Herk, A.M.; Manders, B.G.; Canelas, D.A.; Quadir, M.A.; DeSimone, J.M.
- Book ID
- 126954896
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 90 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0024-9297
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π SIMILAR VOLUMES
Free-radical polymerizations of methyl methacrylate (MMA) and of butyl acrylate (BA) in fluid C02 were studied by means of pulsed laser polymerization (PLP) and molecular weight analysis of the resulting polymer using size-exclusion chromatography (SEC). With the PLP-SEC technique propagation rate c
## Abstract Pulsedβlaser polymerization (PLP) in conjunction with molar mass distribution (MMD) measurement is the method of choice for determining the propagation rate coefficient __k__~p~ in freeβradical polymerizations. The authors, members of the IUPAC Working Party on __Modeling of kinetics an