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Pronounced Supramolecular Order in Discotic Donor–Acceptor Mixtures

✍ Scribed by Wojciech Pisula; Marcel Kastler; Daniel Wasserfallen; Joseph W. F. Robertson; Fabian Nolde; Christopher Kohl; Klaus Müllen

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
543 KB
Volume
45
Category
Article
ISSN
0044-8249

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Mechanically induced radical pair format
Mechanically induced radical pair formation in porphyrin—quinone and related donor—acceptor mixtures. Unusual stability and zero-field splittings
✍ S.D. Chemerisov; O.Ya. Grinberg; D.S. Tipikin; Ya.S. Lebedev; H. Kurreck; K. Möb 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 810 KB

The mechanochemical activation of polycrystalline mixtures of porphyrins and quinones (as well as some other donors and quinones) was found to produce large concentrations of triplet radical pairs with unusual stability in the solid state matrix. Highfield/high-frequency (2 mm band) EPR experiments