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Pronounced Effects of Zero-Point Energy Difference on Intramolecular Electron Transfer in Asymmetric Mixed-Valence Biferrocenium Cations: Structural, EPR, and 57 Fe Mössbauer Characteristics

✍ Scribed by Dong, Teng-Yuan; Chang, Ling-Shao; Lee, Gene-Hsiang; Peng, Shie-Ming

Book ID: 126882655
Publisher: American Chemical Society
Year: 2002
Tongue: English
Weight: 264 KB
Volume: 21
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om0203476

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Electron transfer in chemical''] and biological [2] systems has received considerable attention in the last few years. Recent studies of electron transfer in mixed-valence biferrocenium complexes 1-6 revealed that the environment surrounding a cation is perhaps the most important factor in determini