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Pronounced Effects of Crystal Structures on Intramolecular Electron Transfer in Mixed-Valence Biferrocenium Cations: Structural, EPR, and 57 Fe Mössbauer Characteristics

✍ Scribed by Dong, Teng-Yuan; Ho, Pei-Har; Lai, Xiao-Qian; Lin, Zhi-Wei; Lin, Kuan-Jiuh


Book ID
126087288
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
267 KB
Volume
19
Category
Article
ISSN
0276-7333

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Electron transfer in chemical''] and biological [2] systems has received considerable attention in the last few years. Recent studies of electron transfer in mixed-valence biferrocenium complexes 1-6 revealed that the environment surrounding a cation is perhaps the most important factor in determini