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Promoting effect of coadsorbed CO on the decomposition of saturated hydrocarbons on Ni(755)

โœ Scribed by Hideo Orita; Hiroshi Kondoh; Hisakazu Nozoye


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
444 KB
Volume
228
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


Coadsorption of saturated hydrocarbons and CO has been investigated by temperature-programmed desorption (TPD). Coadsorbed CO promotes the decomposition of low reactive hydrocarbons during TPD. The coverage and decomposition fraction (ratio of decomposed molecules to adsorbed ones) are determined from TPD by using the effect of coadsorbed CO.


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## Abstract Two kinds of ultrafine Coโ€“B amorphous alloy catalysts, denoted as Pโ€1 Coโ€“B and Pโ€2W Coโ€“B, were prepared by chemical reduction with borohydride in aqueous or 50% (v/v) ethanol/water solution, respectively. In comparison with the corresponding Coโ€based crystalline catalysts and Niโ€based c