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Prolongation of fluorescence decay time by structural changes of the environment of the emitting molecule

✍ Scribed by R. Dreher; H. Schomburg


Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
582 KB
Volume
25
Category
Article
ISSN
0009-2614

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✦ Synopsis


Spontaneous emission of oriented moIecules in helical structures is tivestigxted expeximentairy for the case where the structural opacity band coincides with one of the intense emission lines of the motecutes. It is found that the decay time is marked& lengthened compared to the structuxeIess state or to the case where the stop band of the helical structure and the emission lines differ in frequency. Evidence is gven for a 'dynamic state', formed by the molecular states and the electromagnetic field of the standing waves in the stop band.


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