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Proline derived phosphine–oxazoline ligands in the asymmetric Heck reaction

✍ Scribed by Scott R Gilbertson; Zice Fu; Dejian Xie

Book ID
104211482
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
74 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

O Ar L 2 PdArX β-hydride elimination (syn elimination) H 1 2 3 O OTf O H O H + Pd 2 (DBA) 3 1.5 mol% [ligand 5 or 6] 3 mol% diisopropyl amine room temp. solvent

📜 SIMILAR VOLUMES

Asymmetric hydrogenation of aromatic ole
Asymmetric hydrogenation of aromatic olefins catalyzed by iridium complexes of proline derived phosphine–oxazoline ligands
✍ Guopin Xu; Scott R. Gilbertson 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 196 KB

The synthesis of a series of phosphine-oxazoline ligands is reported. This ligands are synthesized by reaction of a phosphine chloride with the secondary nitrogen of proline. Upon coordination to iridium the resulting complexes can be used in the asymmetric hydrogenation of simple olefins. The effec

ChemInform Abstract: Proline-Based P,N L
ChemInform Abstract: Proline-Based P,N Ligands in Asymmetric Allylation and the Heck Reaction.
✍ Scott R. Gilbertson; Dejian Xie; Zice Fu 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v