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Proline-catalyzed asymmetric Diels–Alder reactions of an o-quinodimethane

✍ Scribed by Shirakawa, Hidenori; Sano, Hiroshi

Book ID
124131848
Publisher
Elsevier Science
Year
2014
Tongue
French
Weight
303 KB
Volume
55
Category
Article
ISSN
0040-4039

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Asymmetric induction in Diels-Alder reac
Asymmetric induction in Diels-Alder reactions of o-quinodimethanes
✍ James L. Charlton 📂 Article 📅 1985 🏛 Elsevier Science 🌐 French ⚖ 257 KB

Asymmetric inductive effects have been measured on the Diels-Alder reaction of dimethyl fumarate with o-quinodimethane bearing a chiral u-alkoxy group. The chiral substituents used were f-phenylethoxy, 2-(1-phenyl)propoxy, 1-(2\_phenyl)propoxy, 2-(4-phenyljbutoxy and l-cyclohexylethoxy. The greatest