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Diastereoselection in the intramolecular diels-alder reaction of o-quinodimethanes.

✍ Scribed by Fatima Z. Basha; William J. McClellan; John F. DeBernardis


Book ID
119000167
Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
197 KB
Volume
32
Category
Article
ISSN
0040-4039

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Asymmetric induction in Diels-Alder reac
✍ James L. Charlton πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 French βš– 257 KB

Asymmetric inductive effects have been measured on the Diels-Alder reaction of dimethyl fumarate with o-quinodimethane bearing a chiral u-alkoxy group. The chiral substituents used were f-phenylethoxy, 2-(1-phenyl)propoxy, 1-(2\_phenyl)propoxy, 2-(4-phenyljbutoxy and l-cyclohexylethoxy. The greatest