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Proline Catalyzed Asymmetric Aldol Reaction between Methyl Ketones and α-Ketoesters†

✍ Scribed by Ya-Jun Wang; Zong-Xuan Shen; Bin Li; Ya-Wen Zhang

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
58 KB
Volume
24
Category
Article
ISSN
0256-7660

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Proline-Catalyzed Asymmetric Aldol React
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✍ Ya-Jun Wang; Zong-Xuan Shen; Bin Li; Ya-Wen Zhang 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 21 KB

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## Abstract A concise and enantioselective synthesis of (__S__)‐ethyl 2‐cyclopentyl‐2‐hydroxy‐2‐arylacetate, a key intermediate for the muscarinic receptor, is reported. The tertiary stereogenic center was constructed with good stereoselectivity through the __L‐__proline‐catalyzed direct asymmetric