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Proline-Catalyzed Asymmetric Aldol Reaction Between Methyl Ketones and α-Ketoesters.

✍ Scribed by Ya-Jun Wang; Zong-Xuan Shen; Bin Li; Ya-Wen Zhang

Publisher
John Wiley and Sons
Year
2006
Weight
21 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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Enantioselective Aldol Reaction of α-Ket
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✍ Jiming Xiang; Baolin Li 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 71 KB 👁 1 views

## Abstract A concise and enantioselective synthesis of (__S__)‐ethyl 2‐cyclopentyl‐2‐hydroxy‐2‐arylacetate, a key intermediate for the muscarinic receptor, is reported. The tertiary stereogenic center was constructed with good stereoselectivity through the __L‐__proline‐catalyzed direct asymmetric