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Progress in the Asymmetric Synthesis of 1,2-Diamines from Azomethine Compounds

✍ Scribed by Diego Savoia


Publisher
John Wiley and Sons
Year
2006
Weight
8 KB
Volume
37
Category
Article
ISSN
0931-7597

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## Abstract Oxime ethers 1 react with ammonia and primary amines to give α‐amino oxime ethers. The reaction of α‐bromo oxime ethers with sodium azide affords α‐azido oxime ethers. Hydrogenolysis of the azido compounds using 5% palladium on calcium carbonate as catalyst yields the α‐amino oxime ethe