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Practical Asymmetric Synthesis of 1,2-Diamines in the 3-Aminoazepane Series.

✍ Scribed by S. Cutri; M. Bonin; L. Micouin; H.-P. Husson; A. Chiaroni


Publisher
John Wiley and Sons
Year
2003
Weight
194 KB
Volume
34
Category
Article
ISSN
0931-7597

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Chlorosulfonylated polystyrene, a commodity resin, reacts with enantiopure 1,2-diamines to afford, in a single step, high loading catalytic resins involving monosulfonylated 1,2-diamino moieties. These functional polymers form stable (p-cymene)ruthenium chloride [RuClA C H T U N G T R E N N U N G (p