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Products of the Reactions of 2-Diazomalonate and of 2-Diazoindanedione with Germylenes and Stannylenes

✍ Scribed by Ossig, Günter; Meller, Anton; Freitag, Stefanie; Müller, Olaf; Gornitzka, Heinz; Herbst-Irmer, Regine

Book ID
126976188
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
428 KB
Volume
15
Category
Article
ISSN
0276-7333

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Reactions of bis[bis(trimethylsilyl)meth
Reactions of bis[bis(trimethylsilyl)methyl]germylene and the corresponding stannylene with diazidosilanes
✍ Toshiyuki Ohtaki; Yoshio Kabe; Wataru Ando 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 682 KB

The reactions of bis[bis(trimethyIsilyl)methyl]germylene (1) and the corresponding stannylene (2) with di-tert-butykliazidosilane gave N-(azidosi-1yl)germanimine (4) and the stannanimine (5) in quantitative yields. The structures have been confirmed by single-crystal X-ray diffraction. Crystal data