Products of peracid oxidation of organothiophosphorus compounds
โ Scribed by Bellet, Eugene M.; Casida, John E.
- Book ID
- 127332451
- Publisher
- American Chemical Society
- Year
- 1974
- Tongue
- English
- Weight
- 718 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0021-8561
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๐ SIMILAR VOLUMES
cl-Lactones have been implicated as reactive intermediates in several types of reactions: the solvolysis of cy-halocarboxylate anions,2 the decomposition of certain peresters,
Recent reports describe peracid oxidation studies on cyclopropeues as a potential syuthetic approach to an oxabicyclobutaue derivative.2 Eowever, this hetexocyclic system has not yet been obtained, apparently a result of its facile rearraug-t to the i8americ coojugated carbonyl compound as iudicated
The ready availability of imino ethers from alkylation of amides1 makes them attractive intermediates in the synthesis of new hetergcyclic compounds. We report here on the peracid oxidation of some strained and unstrained imino ethers to alkoxyoxasiranes and the reactivity of these new heterocycles.