Production of peroxidic compounds from phenols by aqueous titanium(IV) - hydrogen peroxide oxidant systems
β Scribed by R.G.R. Bacon; Lai Ching Kuan
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- French
- Weight
- 170 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0040-4039
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## Abstract The hydroxylation of benzene to phenol with hydrogen peroxide was investigated using different solvents and a series of catalysts, obtained by modification of titanium silicalite (TSβ1). The best results were obtained after postβsynthesis treatment of TSβ1 with NH~4~HF~2~ and H~2~O~2~.
Oxidative Chlorination of Acetanilides by Metal Chlorides-Hydrogen Peroxide in Acid-Aqueous Medium Systems. -Introduction of chlorine into the aromatic ring of acetanilides can be achieved by treatment with metal chloride-H2O2-acid systems in aqueous medium. The influence of substituents at the aro