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Production of fungicidal oil and activated carbon from pistachio shell

โœ Scribed by Cagdas Okutucu; Gozde Duman; Suat Ucar; Ihsan Yasa; Jale Yanik


Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
294 KB
Volume
91
Category
Article
ISSN
0165-2370

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โœฆ Synopsis


The main objective of this study was to evaluate the feasibility of pistachio shell as a biomass feedstock for the production of fungicidal oil and a precursor for the production of activated carbon by physical activation. For this purpose, pistachio shell was pyrolyzed in a fixed bed reactor at the different temperatures (300-600 โ€ข C). The pyrolysis products were identified as gas, bio-oil, aqueous solution and char. The product distribution from pyrolysis process did not significantly change when the pyrolysis temperature was above 300 โ€ข C. The pyrolysis gas product had low calorific value since it contained the high proportion of carbon oxides. Because of their high oxygen content, the bio-oils were found not to be used as a fuel. Thus, the bio-oil was tested again four different types of fungi (pathogenetic, wood decaying and saprophyting). It was shown fungicidal activity again all tested fungi at the concentration of 10-50 mg ml -1 . The pyrolysis char was evaluated as a precursor for the production of activated carbon. The surface area and micropore volume of the activated carbon produced from the char by CO 2 activation at 900 โ€ข C were found to be 708 m 2 g -1 and 0.280 cm 3 g -1 , respectively.


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## Abstract Two activated carbons were obtained from pistachio shells by impregnation with H~3~PO~4~ under standard conditions of acid concentration (50 wt%) and heat treatment at 773 K for 2 h. The soaking time was 24 and 72 h for the two samples before thermal pyrolysis. Analysis of the N~2~/77 K