Production of CN(A2Πi) in the photolysis of acetonitrile at 158 nm

✍ Scribed by Joshua B. Halpern; Xiao Tang

• Publisher: Elsevier Science
• Year: 1985
• Tongue: English
• Weight: 428 KB
• Volume: 122
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(85)80580-7

✦ Synopsis

The pnmarl producl or the phololysls or ace~omlr~le and acc~on~Wr-d, m Ihe Tlr\l Rydbrrg system abgorphon nl 158 nm IS \homn 10 be CN(A'n,) Near colhs~on free mcasuremenls or the quantum sidle dlsrnbullons rn the A'n, II'= 0 level drwcl 1111lc romuonal exc~tahon m the CN fragment The population of the 0'=1 level of the cN(~'n,) bmw IS less than 10% or thal III Ihe /I'= 0 Ie\el The occupauon or the &,2

and n,,2 mnmrolds seems IO be staust~cal