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Product state distributions of CN(X) produced in the photodissociation of C4N2 at 160 nm

✍ Scribed by M.J. Sabety-Dzvonik; R.J. Cody; W.M. Jackson

Publisher: Elsevier Science
Year: 1976
Tongue: English
Weight: 263 KB
Volume: 44
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(76)80426-5

No coin nor oath required. For personal study only.

✦ Synopsis

The photolysis of dicyanoacetylenc (CaiUz) at 160 run produces CN(X * 23 mdlcals which arc rotationauy and vibra tionally cxcitcd. Laser-induced fh~orcscence of the CN(X) shows that the radicak are forrned primarily in the IJ = 0 dnd u = 1 vlbrationai levels with a relatlvc population ratio of No: NI : N2 = 0.76: 0.17 : 0.07. The rotational Iinc intensities ate tittcd by IIoltzmann distributions with temperatures of = 1400 K and = 12CO K for the u = 0 and u = 1 Icvck. recpccriveIy. The form of these rotational distributions arc qualitatively explained by a statistical prcdissociation of C4N2.

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