Production and hydrolysis of 3,4-dimethyl-2,5-diphenyl-1,3-oxazolidine
✍ Scribed by Astrová, Martina ;Kurc, Ladislav ;Červený, Libor
- Book ID
- 106512631
- Publisher
- Springer
- Year
- 2006
- Tongue
- English
- Weight
- 84 KB
- Volume
- 89
- Category
- Article
- ISSN
- 0133-1736
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The title compound, C~25~H~29~NO~3~, was prepared in the course of the generation of depsipeptide libraries resembling the Jasplakinolide family of natural products. The dihedral angle between the phenyl ring planes is 74.1 (3)° The oxazolidinone ring adopts a slightly distorted ^4^ __E__ conformati
In the title compound, C 10 H 17 NO 4 , the urethane group is planar and the oxazolidinone ring adopts an envelope conformation. Intermolecular C-HÁ Á ÁO interactions link the screw-and glide-related molecules into a two-dimensional network parallel to (101).
The title compound, C 17 H 18 N 2 O, was obtained by methylation of (4R,5R)-4,5-diphenylimidazolidin-2-one. The C-O bond exhibits double-bond character, and both C-N bonds in the urea group are intermediate between single and double bonds.