Product Branching Ratios in the NH 2 + NO Reaction: A Re-Evaluation
โ Scribed by Park, J.; Lin, M. C.
- Book ID
- 126106611
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 29 KB
- Volume
- 103
- Category
- Article
- ISSN
- 1089-5639
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
We use RRKM theory to calculate rate constants and product branching fractions for NH + NO, comparing results for an ab initio surface and two recent empirical surfaces. In addition we compare trajectory and RRKM branching fractions based on the empirical surfaces, including an assessment of zero-po
Absolute rate coefficients for the reaction NH,+NO were measured by following the OH radical formation at 294-1027 K in a heatable quartz reactor by means of the laser photolysis/laser-induced fluorescence technique. The data fit the expression k, = (7.9 + I .O) x 1 015 T-1~'7ko.25 cm' mol-' SF'. In