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Kinetic measurements and product branching ratio for the reaction NH2+NO AT 294–1027 K

✍ Scribed by B. Atakan; A. Jacobs; M. Wahl; R. Weller; J. Wolfrum

Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
385 KB
Volume
155
Category
Article
ISSN
0009-2614

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✦ Synopsis

Absolute rate coefficients for the reaction NH,+NO were measured by following the OH radical formation at 294-1027 K in a heatable quartz reactor by means of the laser photolysis/laser-induced fluorescence technique. The data fit the expression k, = (7.9 + I .O) x 1 015 T-1~'7ko.25 cm' mol-' SF'. In addition, the branching ratio Binto the OH product channel was determined to be 0.1 + 0.025 at 300 K, p increases with increasing temperature and reaches a value of 0.19 k 0.05 at 1000 K.

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