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Probing the Mechanisms of Enantioselective Hydrogenation of Simple Olefins with Chiral Rhodium Catalysts in the Presence of Anions

✍ Scribed by Jillian M. Buriak; Jason C. Klein; Deborah G. Herrington; John A. Osborn

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
225 KB
Volume
6
Category
Article
ISSN
0947-6539

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The synthesis of enantiomerically enriched (+)-(R)-2-methyl-1-tetralone 1 (up to 29% e.e.) was achieved by enantioselective protonation of the achiral enolate such as 2, using the oxazoline (S)-3 as the source of chirality. Chirality 11:787-789, 1999.