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The Effect of Internal Hydroxy Groups in Chiral Diphosphane Rhodium(I) Catalysts on the Asymmetric Hydrogenation of Functionalized Olefins

✍ Scribed by Armin Börner


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
480 KB
Volume
2001
Category
Article
ISSN
1434-1948

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The influence of two threo-arranged methoxy or hydroxy structural analysis reveals that the oxygen atom of the hydroxy group is by 0.9 A ˚closer to the metal center than that groups as hemilabile ligands in seven-membered (diphosphane)Rh I chelates upon the asymmetric of the methyl ether. 31 P-NMR s