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Probing the Mechanism of 1,4-Conjugate Elimination Reactions Catalyzed by Terpene Synthases

✍ Scribed by Faraldos, Juan A.; Gonzalez, Veronica; Li, Amang; Yu, Fanglei; Köksal, Mustafa; Christianson, David W.; Allemann, Rudolf K.


Book ID
118121902
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
458 KB
Volume
134
Category
Article
ISSN
0002-7863

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CoTPP-catalyzed reaction mechanism of the cycloheptatriene 1.4-endoperoxide is studied. Beside the expected bisepoxide, two isomerit open-chain aldehydes are isolated. The mechanism for the formation of the aldehydes are discussed in terms of radical intermediates.