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Primary reactions in the photolysis of 1,1-dichloro-ethylene

✍ Scribed by R. Ausubel; M.H.J. Wijnen

Publisher
Elsevier Science
Year
1976
Weight
494 KB
Volume
5
Category
Article
ISSN
0047-2670

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Primary processes in the 147-nm photolys
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The room temperature photolysis of 1,l-dichloroethane at 147 nm in the pressure range of 1.34-196.2 torr is characterized almost entirely by the molecular elimination of HCl, Cl,, and small quantities of HD. While it is possible that the C2HD arises, in part, from the decomposition of vibrationally

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The photolysis of n's-l,2-dichloroethylene has been investigated in the presence of 1 2 The results as a function of incident w$velength and as a function of initial cix pressure. indicate that at > 2200A the following primary processes occur: The lifetime of the excited state yielding the above p