𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Primary radicals in the photo-oxidation of aromatics — reactions of xylenols with •OH, N3• and H• radicals and formation and characterization of dimethylphenoxyl, dihydroxydimethylcyclohexadienyl and hydroxydimethylcyclohexadienyl radicals by pulse radiolysis

✍ Scribed by Rita Terzian; Nick Serpone; Marye Anne Fox

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
895 KB
Volume
90
Category
Article
ISSN
1010-6030

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Formation of semiquinone radical in the
Formation of semiquinone radical in the reaction of embelin (2,5-dihydroxy-3-undecyl-1,4-benzoquinone) with reductants as well as oxidants. Characterization by pulse radiolysis and structure investigation by quantum chemical study
✍ Ravi Joshi; Tapan K. Ghanty; Tulsi Mukherjee 📂 Article 📅 2009 🏛 Elsevier Science 🌐 English ⚖ 638 KB

Embelin, 2,5-dihydroxy-3-undecyl-1,4-benzoquinone, has two intra-molecular hydrogen bonds between the quinone and hydroquinone groups present on the same ring. Therefore, it is expected to produce semiquinone radical in the oxidation as well reduction reactions. To investigate this aspect, kinetics

The formation of (CH3)3Ċ, H2ĊC(Me)2OH an
The formation of (CH3)3Ċ, H2ĊC(Me)2OH and ĊH3 radicals in the radiolysis of aqueous t-butyl alcohol: on the solvation of t-butyl alcohol by water
✍ K.V.S. Rao; M.C.R. Symons 📂 Article 📅 1973 🏛 Elsevier Science 🌐 English ⚖ 170 KB

Esppsure of aqueous glassy solutions of f-butyl alcohol to 6oCo vlays at 77°K gave ESR spectra characteristic of h!e& and H2CC(hfe)20H radicals. The results for the former were unusual in fh?t, for very dilute aqueous solutions and for solutions of 0.4 mole fraction through to the pure alcohol, all