Primary Product of the Horseradish Peroxidase-Catalyzed Oxidation of Pentachlorophenol
β Scribed by Kazunga, Chikoma; Aitken, Michael D.; Gold, Avram
- Book ID
- 126924286
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 72 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0013-936X
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π SIMILAR VOLUMES
NMR and mass spectroscopic evidence has been obtained which indicates that the product of the oxidation of o-phenylenediamine by hydrogen peroxide, uncatalyzed or catalyzed by horseradish peroxidase, is 2,3-diaminophenazine. These results settle disparate literature descriptions. The process is most
Ortho-, meta-, and para-phenylenediamines were polymerized using hydrogen peroxide as an oxidant and horseradish peroxidase as a catalyst in mixed solvents of 1,4-dioxane and water. The yield of the polymers was strongly dependent on solvent composition, and maximum yields were obtained at 15-30% 1,