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Primary Electroviscous Effect with a Dynamic Stern Layer: Low κa Results

✍ Scribed by F.J. Rubio-Hernández; E. Ruiz-Reina; A.I. Gómez-Merino


Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
110 KB
Volume
226
Category
Article
ISSN
0021-9797

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✦ Synopsis


The classical treatments of the primary electroviscous effect show important discrepancies with respect to the experimental data. A possible better agreement may be found if the contribution of the ions adsorbed on the Stern layer, which can move tangentially near the particle surface, is taken into account. This contribution has been incorporated into the Watterson-White theory. A study of the influence of the Stern-layer parameters on the primary electroviscous coefficient has been made.


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The Primary Electroviscous Effect: Thin
✍ J.D. Sherwood; F.J. Rubio-Hernández; E. Ruiz-Reina 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 86 KB

The primary electroviscous effect due to the charge clouds surrounding spherical charged particles suspended in an electrolyte was studied by Hinch and Sherwood (J. Fluid Mech. 132, 337 (1983)) in the limit of double layers thin compared to the particle radius a. Here we introduce the effect of a dy

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The theory developed by Watterson and White (Watterson, I. G., and White, L. R., J. Chem. Soc., Faraday Trans. 2 77, 1115 (1981)) to calculate the primary electroviscous coefficient of a suspension of charged spherical colloidal particles has been extended, by considering the presence of a dynamic S