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Prevention of pyrrole polymerization in acidic reaction media

✍ Scribed by Norman W. Gabel


Book ID
112121671
Publisher
Journal of Heterocyclic Chemistry
Year
1967
Tongue
English
Weight
82 KB
Volume
4
Category
Article
ISSN
0022-152X

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The kinetics of the reaction of manganese(III) with oxalic acid (OA) has been studied in H2SO 4 solutions. Under the experimental conditions of 6 x 10 -3 < [OA]o < 0.4mol dm-3 and [H2SO4]o >~ 0.2 mol dm-3 the observed pseudofirst order rate constant kob ~ follows the expression where kl, k2 and K 2