Pressure effects on conformational equilibrium in solution. Infrared studies of halocyclohexanes
β Scribed by Christian, S. D.; Grundnes, J.; Klaboe, P.
- Book ID
- 127383076
- Publisher
- American Chemical Society
- Year
- 1975
- Tongue
- English
- Weight
- 282 KB
- Volume
- 97
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
IR spectra of 2-baloethanoI.s (CH2XCH20H, X = CI, Br, and I) in carbon disulfide were measured at 25Β°C up to 2.5 kbar. The volume changes accompanying the transformation to the Gg conformer of the compounds were -12, eO.5, and +1.3 cm3 moT' for X = Cl, Br, and I, respectively.
## Abstract We investigated the temperature and pressure effects on conformational equilibria of __N__βacetylβLβalanineβ__N__β²βmethylamide (AAlaMA) in aqueous solution by Raman spectroscopy. Scattering intensities in the skeletal stretching mode of AAlaMA in aqueous solution were decomposed into so