Pressure Effect Studies on the Spin-Transition Behavior of a Dinuclear Iron(II) Compound
✍ Scribed by Bhattacharjee, Ashis; Roy, Madhusudan; Ksenofontov, Vadim; Kitchen, Jonathan A.; Brooker, Sally; Gütlich, Philipp
- Book ID
- 120449968
- Publisher
- John Wiley and Sons
- Year
- 2013
- Tongue
- English
- Weight
- 788 KB
- Volume
- 2013
- Category
- Article
- ISSN
- 1434-1948
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## Abstract A dinuclear iron(II) complex containing the new pyridyl bridging ligand, 2,5‐di(2′,2′′‐dipyridylamino)pyridine (ddpp) has been synthesised and characterised by single‐crystal X‐ray diffraction, magnetic susceptibility and Mössbauer spectral methods. This compound, [Fe~2~(ddpp)~2~(NCS)~4
Theeffect oflow pressure @= 150 bar) on the high-spin (HS)-lowrpin (LS) transition in [Fe\_,Znl\_\_~(2-pic)~] Cl,-E1OH (x = OS, 1.0) was measured by Mkbauer spectroscopy and the results compared with theory. The linear dependence of the volume of the lattice on the HS fraction, which is the basic as