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Pressure Effect on CH3 and C2H3 Cross-Radical Reactions

✍ Scribed by Fahr, Askar; Laufer, Allan H.; Tardy, Dwight C.


Book ID
111900230
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
74 KB
Volume
103
Category
Article
ISSN
1089-5639

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Absolute values of the reaction cross section, CT,, for the title reaction family have been measured by chemiluminescence emission under beam-gas conditions. The uR values diminish as the radical group R increases in size, showing an important overall steric effect. These results are discussed in th