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Ab initiostudies on reaction H2C=C(OH)Li+CH3+(CH3-)

✍ Scribed by Yigui Wang; Changjun Sun; Conghao Deng


Publisher
SP Science China Press
Year
1998
Tongue
English
Weight
475 KB
Volume
41
Category
Article
ISSN
1674-7291

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Unimolecular reactions of the isolated i
✍ Richard D. Bowen; Alex. W. Colburn; Peter J. Derrick πŸ“‚ Article πŸ“… 1990 πŸ› John Wiley and Sons 🌐 English βš– 858 KB

The reactions of ten metastable immonium ions of general structure R'R2C=NH+C4H9 (R' = H, R2 = CH, , C2H, ; R' = R2 = CH,) are reported and discussed. Elimination of C4H, is usually the dominant fragmentation pathway. This process gives rise to a Gaussian metastable peak; it is interpreted in terms