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Pressure dependence of the midgap absorption and Raman scattering in a new MX chain complex [Pt(en)2][Pt(en)2Cl2](BF4)4, (en)=ethylenediamine

โœ Scribed by N. Kuroda; M. Nishida; N. Matsushita; M. Yamashita


Book ID
116136499
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
213 KB
Volume
71
Category
Article
ISSN
0379-6779

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Calculations of the resonance Raman excitation profiles for the v, band and its overtones have been performed for the linearchain mixed-valence platinum complex [Pt(en)\*] [Pt(en)zBr,]Br, It is found that the Pt'"-Br bond length increases by 0.075 A in the intervalence state. A satisfactory fit to t