Pressure broadening in the 6190 Å vibration-rotation band of methane
✍ Scribed by Jack Gelfand; Wahid Hermina; William Hayden Smith
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 363 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
A tunable dye 11tser coupled with photoxoustic detection has been utdized to obtain t!x pressure broadening coefficient of the 6196.82 A line in the 6190 A vibration-rotation band of CHa_ The pressure broadening coefficient W-B found to be 0.086 + 0.006 cm-ljatm. This is m close ageement with simiir iines in the fundsmemd and loeer overtone hands of CH.t
;md provides some information about trends in collisional interactions x\ ith incre&n~ \ibratioml excitation.
📜 SIMILAR VOLUMES
Pressure broadening of rotational transitions in the nitric oxide fundamental band was studied using Fourier transform spectroscopy. Rotational level dependent broadening coefficients were determined for both the 2 1/2 and 2 3/2 substates at 300 K using the five noble gases as the broadening species
The anomdous molecular constants pre%iously obtained in a fit to the IJ~ isotrcpic &mrtn vibration-rotation band of methnne. lzCH,, are interpreted ils b&t, 0 due to an effective Coriolirtype interaction between the vt and ~2 \* v4 states, Cllcuhtions which espticitiy t&c into account this interacti