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Interpretation of vibration-rotation constants derived from the υ1 band of methane

✍ Scribed by Jens-Erik Lolck; Alan G. Robiette

Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
505 KB
Volume
64
Category
Article
ISSN
0009-2614

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✦ Synopsis

The anomdous molecular constants pre%iously obtained in a fit to the IJ~ isotrcpic &mrtn vibration-rotation band of methnne. lzCH,, are interpreted ils b&t, 0 due to an effective Coriolirtype interaction between the vt and ~2 * v4 states, Cllcuhtions which espticitiy t&c into account this interaction shoxx quantitarire agreement with e\perimcnt.

📜 SIMILAR VOLUMES

Pressure broadening in the 6190 Å vibrat
Pressure broadening in the 6190 Å vibration-rotation band of methane
✍ Jack Gelfand; Wahid Hermina; William Hayden Smith 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 363 KB

A tunable dye 11tser coupled with photoxoustic detection has been utdized to obtain t!x pressure broadening coefficient of the 6196.82 A line in the 6190 A vibration-rotation band of CHa\_ The pressure broadening coefficient W-B found to be 0.086 + 0.006 cm-ljatm. This is m close ageement with simii