Pressure and Temperature Dependence of the Recombination of p -Fluorobenzyl Radicals
✍ Scribed by Lee, Changyoul; Luther, Klaus; Oum, Kawon; Troe, Jürgen
- Book ID
- 126938995
- Publisher
- American Chemical Society
- Year
- 2006
- Tongue
- English
- Weight
- 141 KB
- Volume
- 110
- Category
- Article
- ISSN
- 1089-5639
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📜 SIMILAR VOLUMES
The photoinduced formation of radical ion pairs (in fluorescence quenching) and their geminate recombination to give singier &round state) and triplet product states IS studied at different temperatures between 233 and 296 K with the system pyrene/N,Ndimeth&mline (DMA) in methanol. l%e geminate sing
I%c rate conswnt for methyl rzdic;ll recombination has been measured over the rempcrature range 296-577 K and at pressures bcl\vcrn 5 and 500 Torr win: laser 5~11 photolysis. coupled with absorption spectroscopy at 216.36 nm. Analysis 01' lhC f~ll-ol'f curves gives k, = (1.78 2 0.18) x IO-" rsp( 151