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Temperature dependence of the geminate recombination of radical ion pairs

✍ Scribed by Heinrich Schomburg; Hubert Staerk; Albert Weller; Hans-Joachim Werner

Publisher: Elsevier Science
Year: 1978
Tongue: English
Weight: 443 KB
Volume: 56
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(78)89001-0

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✦ Synopsis

The photoinduced formation of radical ion pairs (in fluorescence quenching) and their geminate recombination to give singier &round state) and triplet product states IS studied at different temperatures between 233 and 296 K with the system pyrene/N,Ndimeth&mline (DMA) in methanol. l%e geminate singlet recombination yield is found to be strongly increasing with decreasing temperature, whereas the triplet yield is virtually independent of temperature. These results are in agreement with previous theoretical predictions.

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