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Pressure and Temperature Dependence of the Reaction of Vinyl Radical with Ethylene †

✍ Scribed by Ismail, Huzeifa; Goldsmith, C. Franklin; Abel, Paul R.; Howe, Pui-Teng; Fahr, Askar; Halpern, Joshua B.; Jusinski, Leonard E.; Georgievskii, Yuri; Taatjes, Craig A.; Green, William H.

Book ID
126884106
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
266 KB
Volume
111
Category
Article
ISSN
1089-5639

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Absolulc KIIC constants for the rcac11on ofOH WIII acctylcnc wcrc dctcrmmcd at 297 and 419 K for thu 101.d pru~rc\ ol'20-403 Torr usmg a flash photolysa-rcsonancc lluorcsccnre tcchmquc The rate coclTic~cnt k was found to bc pwrurc dcpcndcnt below 200 Torr at both 297 and 429 K, but \\a m the high-pr