Asymmetric allylic alkylation using a po
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Maria Michela DellβAnna; Piero Mastrorilli; Cosimo Francesco Nobile; Gian Paolo
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Article
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2003
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Elsevier Science
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English
β 80 KB
Polymer-supported Pd(AAEMA) 2 (Pd-pol) [AAEMA -: deprotonated form of 2-(acetoacetoxy)ethyl methacrylate] in the presence of chiral ligands catalyses the asymmetric substitution of rac-1,3-diphenyl-2-propenyl acetate with dimethyl malonate. A series of conventional ligands were tested: the enantiose