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Preparation and application of polymer-supported π-allylpalladium complex as a chiral catalyst in the asymmetric allylic alkylation

✍ Scribed by H.-J. Park; Jin Wook Han; Hwimin Seo; Hye-Young Jang; Young Keun Chung; Junghun Suh


Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
102 KB
Volume
174
Category
Article
ISSN
1381-1169

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Asymmetric allylic alkylation using a po
✍ Maria Michela Dell’Anna; Piero Mastrorilli; Cosimo Francesco Nobile; Gian Paolo 📂 Article 📅 2003 🏛 Elsevier Science 🌐 English ⚖ 80 KB

Polymer-supported Pd(AAEMA) 2 (Pd-pol) [AAEMA -: deprotonated form of 2-(acetoacetoxy)ethyl methacrylate] in the presence of chiral ligands catalyses the asymmetric substitution of rac-1,3-diphenyl-2-propenyl acetate with dimethyl malonate. A series of conventional ligands were tested: the enantiose